TY - BOOK AU - Lister,Ted AU - Renshaw,Janet TI - New understanding chemistry for advanced level SN - 9780748739585 AV - QD42 .L57 2000 PY - 2000/// CY - Cheltenham PB - Nelson Thornes KW - Chemistry N1 - Includes Index; Acknowledgements vi Preface vii PART A: FOUNDATIONS Introduction 1 (1) Atomic structure and bonding 2 (8) Inside the atom 2 (2) Bonding 4 (6) The Periodic Table 10 (6) The arrangement of the Periodic Table 10 (1) Using the Periodic Table 11 (3) Trends across a period 14 (1) Predicting formulae of simple ionic compounds 15 (1) Moles 16 (4) Counting atoms 16 (1) Relative atomic mass, Ar 16 (1) Relative molecular mass, Mr 16 (1) The mole 17 (2) Moles and formulae 19 (1) Equations 20 (6) Chemical change 20 (1) Word equations 20 (1) Symbol equations 20 (2) Using the balanced symbol equation 22 (2) Equations using ions 24 (2) Physics and mathematics background 26 (9) Ideas from mathematics and physics 26 (1) Waves 26 (2) Electricity 28 (1) Force, pressure and momentum 29 (1) Mathematics 30 (5) PART B: FUNDAMENTALS Atomic and nuclear structure 35 (21) Introduction 36 (1) Subatomic particles 36 (5) The arrangement of electrons in atoms 41 (7) Nuclides and isotopes 48 (1) The mass spectrometer 49 (2) The 12C scale of atomic masses 51 (1) Summary 52 (1) Practice questions 53 (1) Examination questions 54 (2) Energetics 56 (23) Introduction 57 (1) What is energy? 57 (3) Measurement of enthalpy changes: calorimetry 60 (5) Hess's law 65 (5) Bond enthalpies 70 (3) Why do chemical reactions take place? 73 (2) Summary 75 (2) Practice questions 77 (1) Examination questions 78 (1) Bonding and structure 79 (29) Introduction 80 (1) Bonding 80 (18) Structure 98 (6) Summary 104 (2) Practice questions 106 (1) Examination questions 107 (1) Intermolecular forces: liquids and solutions 108 (16) Introduction 109 (1) Intermolecular forces 109 (8) Mixtures and solutions 117 (4) Summary 121 (1) Practice questions 121 (1) Examination questions 122 (2) Equilibrium 124 (14) Introduction 125 (1) The characteristics of equilibrium 125 (1) Chemical equilibrium 126 (5) The effect of changing conditions on equilibria 131 (2) Measurement of equilibrium constant Kc 133 (1) Industrial applications 134 (1) Summary 135 (1) Practice questions 136 (1) Examination questions 137 (1) Acids and bases 138 (10) Introduction 139 (1) The reactions of acids 139 (1) Theories of acidity 139 (2) Measurement of acidity 141 (5) Summary 146 (1) Practice questions 146 (1) Examination questions 147 (1) Redox reactions 148 (10) Introduction 149 (1) Oxidation and reduction 149 (1) Oxidation numbers 150 (2) Uses of oxidation numbers 152 (4) Summary 156 (1) Practice questions 156 (1) Examination questions 157 (1) Kinetics 158 (17) Introduction 159 (1) Factors which affect the rate of chemical reactions 159 (1) Measuring reaction rates 160 (1) Experimental methods for measuring reaction rates 161 (2) The rate expression 163 (2) Theories of reaction rates 165 (2) Catalysts 167 (5) Summary 172 (1) Practice questions 173 (1) Examination questions 174 (1) Periodicity 175 (15) Introduction 176 (1) The structure of the Periodic Table 176 (2) Periodicity of physical properties 178 (5) Periodicity of chemical properties 183 (4) Summary 187 (1) Practice questions 188 (1) Examination questions 188 (2) The s-block elements 190 (15) Introduction 191 (1) Physical properties of the elements 191 (3) Chemical reactions of the elements 194 (1) Compounds of the s-block elements 195 (6) Summary 201 (2) Practice questions 203 (1) Examination questions 203 (2) The Group VII elements: the halogens 205 (12) Introduction 206 (1) The elements 206 (1) Fluorine and its compounds 207 (1) The other halogens (chlorine, bromine and iodine) 208 (2) Compounds of chlorine, bromine and iodine 210 (3) Economic importance of Group VII 213 (1) Summary 214 (1) Practice questions 215 (1) Examination questions 215 (2) Fundamentals of organic chemistry 217 (30) Introduction 218 (1) Reasons for the variety of carbon chemistry 218 (2) Bonding in carbon compounds 220 (2) Formulae of carbon compounds 222 (3) Naming organic compounds 225 (6) Families of organic compounds 231 (1) Isomers 232 (3) The physical properties of organic compounds 235 (2) The reactivity of organic compounds 237 (6) Equations in organic chemistry 243 (1) Summary 243 (2) Practice questions 245 (1) Examination questions 246 (1) Alkanes 247 (13) Introduction 248 (1) Formulae, naming and structure 248 (2) Isomerism 250 (1) Physical properties 251 (1) Reactions of alkanes 251 (3) Sources of alkanes 254 (1) Economic importance of alkanes 255 (2) Summary 257 (1) Practice questions 258 (1) Examination questions 258 (2) Alkenes 260 (18) Introduction 261 (1) Formulae, naming and structure of alkenes 261 (2) Physical properties of alkenes 263 (1) Reactivity of alkenes 263 (1) Reactions of alkenes 263 (7) Preparation of alkenes 270 (2) Economic importance of alkenes 272 (2) Summary 274 (2) Practice questions 276 (1) Examination questions 276 (2) Haloalkanes 278 (17) Introduction 279 (1) Formulae, naming and structure 279 (2) Physical properties of haloalkanes 281 (1) Reactivity of haloalkanes 281 (1) Reactions of haloalkanes 282 (6) Preparation of haloalkanes 288 (1) Haloalkanes 289 (1) Economic importance of haloalkanes 289 (2) Summary 291 (2) Practice questions 293 (1) Examination questions 294 (1) Alcohols 295 (24) Introduction 296 (1) Formulae, naming and structure 296 (3) Physical properties 299 (1) Reactivity of alcohols 299 (1) Reactions of alcohols 300 (9) Preparation of alcohols 309 (1) Chemistry of economic importance of alcohols 310 (5) Summary 315 (2) Practice questions 317 (1) Examination questions 318 (1) PART C: FURTHER CHEMISTRY Further equilibrium 319 (19) Introduction 320 (1) Phase equilibria 320 (7) Gaseous equilibria 327 (4) The effect of changing conditions on gas-phase equilibria 331 (3) Measuring Kp 334 (1) Summary 335 (1) Practice questions 336 (1) Examination questions 337 (1) More on acids and bases 338 (15) Introduction 339 (1) The dissociation of weak acids and bases 339 (2) pH changes during acid--base titrations 341 (9) Summary 350 (1) Practice questions 351 (1) Examination questions 351 (2) Further redox: electrochemical cells 353 (16) Introduction 354 (1) Electrochemical cells 354 (8) Predicting whether a redox reaction could take place (the feasibility of the reaction) 362 (4) Summary 366 (1) Practice questions 367 (1) Examination questions 368 (1) Further kinetics 369 (13) Introduction 370 (1) Determination of the order of a reaction from experimental data 370 (5) Reaction mechanisms 375 (3) Summary 378 (2) Practice questions 380 (1) Examination questions 381 (1) Gases 382 (11) Introduction 383 (1) The gas laws 383 (3) Measurement of relative molecular mass 386 (1) Dalton's law of partial pressures 387 (1) Kinetic theory 387 (2) Real gases: deviations from the ideal gas equation 389 (1) Summary 390 (1) Practice questions 391 (1) Examination questions 391 (2) Thermodynamics: enthalpy, entropy and free energy 393 (15) Introduction 394 (1) Entropy 394 (5) Free energy change, ΔG 399 (3) Reaction feasibility and temperature 402 (3) Summary 405 (1) Practice questions 406 (1) Examination questions 407 (1) Structure determination 408 (21) Introduction 409 (1) Structure determination of solids with giant structures 409 (4) Structure determination of molecular substances 413 (12) Summary 425 (1) Practice questions 426 (2) Examination questions 428 (1) The p-block elements 429 (35) Introduction 430 (1) Group IV 431 (12) Group V 443 (12) Group VI 455 (7) Examination questions on s- and p-block elements in general 462 (2) The d-block elements 464 (32) Introduction 465 (1) Similarities between the d-block elements 465 (2) Physical properties of d-block elements 467 (1) Chemical properties of d-block elements 467 (14) Examples of the chemistry of some d-block elements 481 (8) Economic importance of the d-block elements 489 (4) Summary 493 (1) Practice questions 494 (1) Examination questions 494 (2) Arenes 496 (34) Introduction 497 (1) Bonding and structure of benzene 497 (5) Naming aromatic compounds 502 (1) Physical properties of arenes 503 (1) Reactivity of arenes 504 (1) Reactions of arenes 504 (7) Chemical evidence for the bonding and structure of benzene 511 (1) Reactions of side chains 512 (2) Preparation of arenes 514 (1) Economic importance of arenes 514 (1) Haloarenes 514 (3) Phenols 517 (7) Summary 524 (4) Practice questions 528 (1) Examination questions 528 (2) Carbonyl compounds 530 (23) Introduction 531 (1) Formulae, naming and structure 531 (2) Physical properties of carbonyl compounds 533 (1) The reactivity of carbonyl compounds 534 (1) Reactions of carbonyl compounds 534 (6) Preparation of carbonyl compounds 540 (1) Carbohydrates 540 (5) Economic importance of carbonyl compounds 545 (3) Summary 548 (3) Practice questions 551 (1) Examination questions 551 (2) Carboxylic acids and their derivatives 553 (21) Introduction 554 (1) Formulae, naming and structure 555 (3) Physical properties of carboxylic acids 558 (1) Reactivity of carboxylic acids 558 (2) Reactions of carboxylic acids 560 (2) Preparation of carboxylic acids 562 (1) Acid derivatives 563 (6) Economic importance of carboxylic acids and their derivatives 569 (1) Summary 570 (2) Practice questions 572 (1) Examination questions 573 (1) Organic nitrogen compounds 574 (25) Introduction 576 (1) Amines 576 (15) Nitriles 591 (2) Summary 593 (4) Practice questions 597 (1) Examination questions 597 (2) Polymers 599 (20) Introduction 600 (1) Proteins 600 (8) Synthetic polymers 608 (7) Summary 615 (1) Practice questions 616 (1) Examination questions 617 (2) Synthetic routes 619 (11) Introduction 620 (1) Basic ideas 620 (1) Methods of preparation of functional groups 621 (1) Reagents used in organic chemistry 621 (3) Examples of reaction schemes 624 (4) Practice questions 628 (1) Examination questions 628 (2) Identifying organic compounds 630 (22) Introduction 631 (1) Finding the structure of an unknown compound 631 (9) Infra-red spectroscopy in organic chemistry 640 (5) Mass spectrometry in organic chemistry 645 (2) NMR in organic chemistry 647 (1) Summary 648 (1) Practice questions 649 (1) Examination questions 650 (2) Answers 652 (12) Further questions 664 (6) Index 670 (10) Periodic Table 680 ER -